64 bits can take or address up to 2^64 of physical RAM but as for performance it is the Application or OS that should be optimized to such architectures in order to work more efficiently and in our native CPU usage we wont notice this much performance difference but in Matrix and other astronomical or mathematical equations the performance is of course better. The PS2 had a 128-Bit CPU or it is marketed this way for unknown reasons becasue no game uses this but it could be used for guided missiles.(Like Sony did with Psones GPU it had some unknown specs that were not released to the public
check this.
The custom instruction set consists of 107 instructions for operating on four 32-bit, eight 16-bit or sixteen 8-bit integers simultaneously. Instructions defined include: add, subtract, multiply, divide, min/max, shift, logical, leading-zero count, 128-bit load/store and 256-bit to 128-bit funnel shift in addition to some not described by Sony for competitive reasons.