The dual channel kits are not labelled and priced differently because they are dual channel...they are so because they are:
1) More stable
2) OC higher
3) come with better voltage regulation and such
4) have heatspreaders
5) Have different clockspeeds for different markets
Getting 2 identical RAM sticks would mostly get you dual channel automatically, without them having to be a kit. But there are always compatibility issues with motherboards that one usually has to make sure of before he buys a motherboard.
As for RAM sticks being installed in incorrect slots, the traces in the PCB leading from the RAM sticks to the memory controller in the CPU work only in the way specified in the manual...meaning you have to place the 2 sticks in the designated slots because ONLY in this way will they run dual channel. The other slots are connected to other pins and into the memory controller differently.
In a nutshell: It is impossible to have dual channel working if you do not follow the correct placements in the RAM slots.
Oh and about pricing:
http://www.amazon.com/Corsair-Vengeance-240-Pin-Platforms-CMZ8GX3M2A1600C9/dp/B004CRSM4I/ref=sr_1_2?ie=UTF8&qid=1345331718&sr=8-2&keywords=corsair+vengeance
8GB DDR3-1600 @ $50 dual channel kit...pricing is really normal...only in Lebanon they are priced so much higher ;)
Kits like this, released recently, have killed the market for budget oriented RAM sticks outside Lebanon. However, here, things are always different...